LC/MS Report File D:\\DATA\\A02\\MONITOR\\CPK2017-320-12997-46622-LCMSA002.D Injection Date : 21 Mar 17 2:36 pm +0800 Tgt Mass(EZX) : 357.80 Sample Name : CPK2017-320-12997 Location : P1-F-03 Acq. Operator : A02-MONITOR Inj : 1 Spec. Reported : MS Integration Inj Volume : 1 ul Acq. Method : D:\\METHODS\\1-POS-3MIN-MON.M Analysis Method : D:\\METHODS\\1-POS-3MIN-MON.M Catalog No:HY-14397 Batch#12997 Easy-Access Method: '1-POS-3MIN-MON' 357.80 Method Info : Mobile Phase: A: water(0.01%TFA) B:ACN(0.01%TFA) Gradient: 5%B increase to 95%B within 1.6 min, 95%B for 1.4min,back to 5%B within 0.01min Flow Rate:2.0ml/min Column :SunFire C18, 4.6*50mm, 3.5um Oven Temperature : 50C*ADC1 A, ADC1 CHANNEL A mAU5000.5*DAD1 A, Sig=214,4 Ref=off mAU500000.5*DAD1 B, Sig=254,4 Ref=off mAU500000.51 MSD1 TIC, MS File ES-API, Pos, Scan, Frag: 704000020000000.511.5 Ion 358.8, MSD1 358.8,Target Mass 357.8 +H Positive, EIC=358.5:359.5 50002500000.5 Integration Results for DAD1 A, Sig=214,4 Ref=off11.522.5min1.6621.65211.51.65622.5min*11.51.65622.5min*1.51.66122.5min*22.5min RetTim Width Area Height Area%|-------|--------|--------------|--------------|--------| 1.66 0.02 1117.92 1159.91 100.00 Integration Results for DAD1 B, Sig=254,4 Ref=off RetTim Width Area Height Area%|-------|--------|--------------|--------------|--------| 1.66 0.02 693.46 751.90 100.00LCMSA002 3/21/2017 2:40:03 PM A02-MONITORPage 1 of 2
LC/MS Report
800070006000500040003000200010000 113.1 128.0 145.8 167.0 187.4 206.0 226.1 244.9 261.2 279.3 294.2 323.0 342.3 357.7 359.1 374.0 358.1 ES-API Positive200300400 395.6 412.2LCMSA002 3/21/2017 2:40:03 PM A02-MONITOR
451.7Ret. Time: 1.66 <<<< POSITIVE SPECTRA >>>>500600700800 496.0 512.3 526.2 552.7 566.9 587.1 621.5 641.0 665.1 690.0 730.3 760.6 832.2 865.8Page
900m/z2 of 2
972.5